• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
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    • 专利摘要:

    公开号:ES2717225T9
    申请号:ES12766813T
    申请日:2012-09-18
    公开日:2020-02-03
    发明作者:Prakash Govindan；Gregory Thiel；Ronan Mcgovern；John Lienhard；Mostafa Elsharqawy
    申请人:King Fahd University of Petroleum and Minerals；Massachusetts Institute of Technology；
    IPC主号:
    专利说明:

    [0001] Bubble column steam mix condenser
    [0002] Background
    [0003] In this century, the shortage of fresh water will overcome energy shortages as a global concern for humanity, and these two challenges are inexorably linked, as explained in the "Special Water Report" in the May 20 issue of 2010 from The Economist. Fresh water is one of the most fundamental needs of human beings and other organisms; Each human being needs to consume a minimum of approximately two liters per day. The world also faces greater demands for fresh water from agricultural and industrial processes.
    [0004] The risks posed by an insufficient water supply are particularly serious. A shortage of fresh water can lead to a variety of crises, including famine, disease, death, forced mass migration, conflict / war between regions, and collapsed ecosystems. Despite the criticality of the need for fresh water and the profound consequences of scarcity, fresh water supplies are particularly limited. 97.5% of the water on Earth is salty, and about 70% of the rest is enclosed in ice (mainly in ice caps and glaciers), leaving only a fraction of all the water on Earth as fresh water (not saline) ) available.
    [0005] In addition, the Earth's water that is fresh and available is not evenly distributed. For example, densely populated countries, such as India and China, have many regions that are subject to scarce supplies. Even more, the supply of fresh water is often seasonally inconsistent. Meanwhile, freshwater demands are intensifying across the globe. The reservoirs are drying up; aquifers are declining; Rivers are dying and glaciers and ice caps are shrinking. The increase in populations increases demand, as do changes in agriculture and greater industrialization. Climate change poses even more threats in many regions. Consequently, the number of people facing water scarcity is increasing. However, naturally occurring fresh water is typically confined in regional drainage basins; and water transportation is expensive and consumes a lot of energy.
    [0006] On the other hand, many of the existing processes to produce fresh water from seawater (or, to a lesser extent, brackish water) require massive amounts of energy. Reverse osmosis (RO) is currently the leading desalination technology. In large-scale plants, the specific electricity required can be as reduced as 4 kWh / m3 for a 30% recovery, compared to the theoretical minimum of about 1 kWh / m3; smaller-scale Ro systems (for example, on board ships) are less efficient.
    [0007] Other existing seawater desalination systems include sudden multi-stage distillation (MSF) based on thermal energy and multi-effect distillation (MED), which are processes that require large amounts of energy and capital. However, in the MSF and MED systems, the maximum brine temperature and the maximum temperature of the heat input are limited to prevent precipitation of calcium sulfate, which leads to the formation of scale in the heat transfer equipment .
    [0008] Humidification-dehumidification (HDH) desalination systems include a humidifier and a dehumidifier as their main components and use a carrier gas (e.g. air) to communicate energy between the heat source and the brine. In the humidifier, the warm sea water comes into direct contact with the dry air, and this air is heated and humidified. In the dehumidifier, the hot and humidified air is contacted (indirectly) with the cold sea water and dehumidified, producing pure water and dehumidified air. Some of the present inventors were also inventors of the following patent applications that include an additional discussion related to HDH processes to purify water: US application. u. No. Series 12 / 554,726, filed on September 4, 2009 (file number of lawyer mit-13607); US request UU. No. Series 12 / 573,221, filed on October 5, 2009 (file number of lawyer mit-13622); and the US request. UU. No. Series 13 / 028,170, filed on February 15, 2011 (lawyer file number mit-14295).
    [0009] A methodology from the University of Florida, which is described in US Pat. UU. No. 6,919,000 B2, reduced the thermal resistance associated with non-condensable gases by using a direct contact condenser instead of a standard indirect contact dehumidifier. This method increases the rates of heat transfer in the condenser at the expense of energy efficiency, since the energy of the humid air entering the dehumidifier is not recovered directly to preheat the seawater. Therefore, although the cost of the dehumidification device is reduced, the energy costs increase.
    [0010] GB698966 refers to improvements in, or related to, liquids, gases or vapors of refrigeration, condensation or absorption apparatus. that have a strong corrosive or pickling action. US 2002/053505 refers to a horizontal distillation apparatus. US 4762593 refers to an apparatus of distillation. US 4,252,546 refers to a process and apparatus for the recovery of solvent from the exhaust air of dry cleaning machines. US 2010/314238 refers to a hybrid solar desalination system. US 3,583,895 refers to a process of heating and evaporation of solutions, and condensation of vapors formed therefrom. US 5290403 refers to a liquid evaporation apparatus.
    [0011]
    [0012] Compendium
    [0013]
    [0014] The single-stage and multi-stage bubble column vapor mixing condensers (simply referred to as condenser elsewhere in this document) and the operation thereof are described herein. Various embodiments of the apparatus and methods may include some or all of the elements, features and steps described below.
    [0015]
    [0016] In the multi-stage bubble column condenser, a fluid source supplies a carrier gas stream that includes a condensable fluid. The multi-stage capacitor includes at least a first stage and a second stage, each of which includes an input, an output and a chamber in fluid communication with the input and output. The input of the first stage of the bubble column condenser is coupled with the fluid source, and the output of the first stage is in fluid communication with the input of the second stage to facilitate the flow of the carrier gas stream from the source of fluid through the chamber of the first stage and then through the chamber of the second stage. The condensable fluid in the liquid phase fills the chambers of the first stage and the second stage, so that the carrier gas stream passes through in direct contact with the liquid, which is stationary or in countercurrent with the carrier gas stream, when it passes from the entrance to the exit of each stage.
    [0017]
    [0018] The present invention relates to a humidification-dehumidification system according to claim 1. The system comprises a humidifier that includes a carrier gas inlet and a carrier gas outlet; a liquid inlet and a liquid outlet, wherein the liquid inlet is coupled with a source of liquid; and a chamber in which the liquid introduced from the liquid inlet may come into contact with a carrier gas containing a condensable fluid in the vapor phase that is introduced from the carrier gas inlet in a countercurrent arrangement and in which a portion of the liquid can be vaporized in the carrier gas; a bubble column vapor mixing condenser that includes at least a first stage that includes a carrier gas inlet, a carrier gas outlet and a chamber containing a liquid bath in fluid communication with the carrier gas inlet and the carrier gas outlet, where the condenser carrier gas input is in fluid communication with the humidifier carrier gas outlet, where the condenser carrier gas outlet is in fluid communication with the humidifier carrier gas input, in where the condenser carrier gas inlet is a bubble generator placed in contact with the liquid bath, so that the carrier gas can bubble up through the liquid bath from the bubble generator, overcoming a hydrostatic charge of the bath of liquid, and where the exit of the carrier gas is placed with an opening for the extraction of the carrier gas above the liquid bath, c by omitting the bubble column vapor mixing condenser, in addition, a conduit that extends through the liquid bath in the chamber and coupled with the liquid source and with the liquid inlet of the humidifier for the liquid to flow from the source, through the condenser chamber, where the liquid can be preheated by recovering energy from the condensation, to the humidifier; and wherein the system further comprises a blower or compressor configured to pump the carrier gas: from the outlet of the carrier gas of the humidifier to the entrance of the carrier gas of the condenser through a conduit, and through the bubble generator, thus allowing to the carrier gas bubble through the liquid bath.
    [0019]
    [0020] The present invention also relates to a method according to claim 7 for condensing a fluid from a carrier gas stream. The method comprises: using a blower or compressor to pass a stream of carrier gas through a humidifier and out of the humidifier through a conduit, where, in the humidifier, a condensable fluid in the vapor phase is added to the stream of carrier gas into a chamber by introducing a liquid through a liquid inlet, thus coming into contact with a carrier gas containing a condensable fluid in the vapor phase that is introduced from a carrier gas inlet in a countercurrent arrangement and in that a portion of the liquid can vaporize in the carrier gas; using a bubble generator to bubble the carrier gas stream comprising the condensable fluid in the vapor phase through a first bath of the liquid phase fluid in a first stage of a bubble column condenser, wherein the gas stream The carrier comes into contact with the first bath, and in which part of the vapor phase fluid in the carrier gas stream condenses in the first bath; the carrier gas stream leaving with a reduced vapor phase fluid content from the first stage of the bubble column condenser and passing the carrier gas stream back through the humidifier through a conduit, where, in the humidifier , additional vapor phase fluids are added to the carrier gas stream after the carrier gas stream has left the first stage; and passing the liquid through a conduit that passes through the fluid in the liquid phase in the first stage to recover the energy of condensation in the bubble column condenser towards the liquid that passes through the conduit before the liquid enter through the liquid inlet of the humidifier.
    [0021] The apparatus and methods can be used to separate pure water from a liquid mixture (which includes, but is not limited to, seawater, brackish water and wastewater) in a cost-effective manner, which can result in substantially reduced costs. compared to the previous methodologies. The embodiments of the apparatus and the methods can offer numerous advantages. First, based on the data of the bubble columns provided in the available literature, the heat transfer coefficient in the multi-stage bubble column condenser is estimated to be 7 kW / m2 • K (ie, at less an order of magnitude greater than in the current state of the art). This heat transfer coefficient is comparable, if not higher, to the condensation of the vapor film. Second, the high energy recovery can be maintained using a novel multi-stage technique. Thirdly, multiple extraction in the apparatus and methods can be used to further increase heat recovery. Fourth, the overall cost of the system is reduced as both the energy cost and the cost of the equipment are reduced.
    [0022] Brief description of the drawings
    [0023] FIG. 1 is a sectional illustration of a single stage bubble column condenser.
    [0024] FIG. 2 is a schematic illustration of an embodiment of a humidification-dehumidification water purification system that includes a multi-stage bubble column condenser. FIG. 3 Trace the temperature profile through the columns in a multi-stage bubble condenser from the top of the bubble columns.
    [0025] FIG. 4 plot the temperature profile in a single stage bubble column condenser from the top of the bubble column.
    [0026] FIG. 5 is a schematic illustration of an embodiment of a multi-extraction humidification-dehumidification water purification system that includes a multi-stage bubble column condenser.
    [0027] In the accompanying drawings, similar reference characters refer to equal or similar parts in the different views; and the apostrophes are used to differentiate multiple instances of the same or similar elements that share the same reference number. The drawings are not necessarily to scale, but emphasis is placed on illustrating particular principles, discussed below.
    [0028] Detailed description
    [0029] The foregoing and other features and advantages of various aspects of the invention (s) will be apparent from the following, more particular, description of various specific concepts and embodiments within the broader limits of the invention (s) ( it is). Various aspects of the subject presented above and discussed in greater detail below can be implemented in any of numerous ways, since the subject is not limited to any particular form of implementation. Examples of specific implementations and applications are provided primarily for illustrative purposes.
    [0030] Unless otherwise defined, used or characterized herein, the terms used in this document (including technical and scientific terms) should be construed as having a meaning that is consistent with its meaning accepted in the context. of the relevant technique and should not be interpreted in an idealized or overly formal sense, unless expressly so defined in this document. For example, if reference is made to a particular composition, the composition can be substantially, although not perfectly pure, since practical and imperfect realities can occur; for example, the potential presence of at least traces of impurities (for example, less than 1 or 2% by weight or volume) can be understood as being within the scope of the description; Similarly, if reference is made to a particular form, the form is intended to include imperfect variations of ideal forms, for example, due to machining tolerances.
    [0031] Although the terms first, second, third, etc., may be used herein to describe various elements, these elements should not be limited by these terms. These terms are simply used to distinguish one element from another. Therefore, a first element, discussed below, could be called a second element without departing from the teachings of the example embodiments.
    [0032] Spatially relative terms, such as "up", "down", "left", "right", "front", "behind" and the like, can be used herein for ease of description when describing the relationship of an element with another element, as illustrated in the figures. It will be understood that the spatially relative terms, as well as the configurations illustrated, are intended to cover different orientations of the apparatus in use or operation in addition to the orientations described herein and represented in the figures. For example, if the apparatus is turned around in the figures, the elements described as "below" or "below" other elements or characteristics would then be oriented "above" the other elements or characteristics. Therefore, the example term, "above," may encompass an orientation both above and below. The apparatus may be oriented in another way (for example, rotated 90 degrees or in other orientations) and the spatially relative descriptors used herein should be interpreted accordingly.
    [0033] Moreover, in this description, when an element is referred to as being "in", "connected to" or "coupled to" another element, it may be directly in, connected or coupled to the other element or intermediate elements may be present unless otherwise specified.
    [0034]
    [0035] The terminology used herein is intended to describe particular embodiments and is not intended to be limiting of example embodiments. As used herein, singular forms, such as "a", "one" and "a", are also intended to include plural forms, unless the context indicates otherwise. Furthermore, the terms "includes", "including", "comprises" and "comprising", specify the presence of the indicated elements or steps, but do not exclude the presence or addition of one or more additional elements or steps.
    [0036]
    [0037] The presence of non-condensable gases can dramatically increase the thermal resistance associated with the condensation of the vapor film on a cold surface. For the typical molar fraction (approximately 70%) of the air (non-condensable gas) present in a dehumidifier (condenser) of a humidification-dehumidification system, the heat transfer coefficient can be as low as 1/100 of that of the pure vapor condensation (in multi-effect and sudden multi-stage distillation systems). In absolute value, the heat transfer coefficient can be as low as 10 W / m2 • K. Therefore, it is advantageous to reduce the thermal resistance associated with the non-condensable gas, while at the same time the advantageous increase in the energy efficiency favored by the methods described in the previous patent applications of the inventors, indicated in the Background.
    [0038]
    [0039] A sectional view of an embodiment of a single stage bubble column condenser 12 is provided in FIG. 1. Bubble column 14 contains a bath of a liquid 15 (for example, distilled water in this embodiment). The liquid 15 is supported on a bubble generator 44 within the bubble column chamber. The gas chambers 17 and 19 are located respectively below and above the liquid. The chamber 17 below the liquid allows a wet carrier gas to be pumped from the conduit 32 'through a compressor / blower 34 through the orifices of the bubble generator 44 to the liquid 15 in the form of bubbles 21, although the lower chamber 17 it can be omitted where the bubble generator 44 includes a network of perforated pipes through which the carrier gas is pumped. A coil 20 that is coupled with a source of fluid (e.g., seawater) winds through water 15 in condenser 12, allowing heat transfer from water 15 in the chamber to seawater that is conducted to through the coil 20. Consequently, the cold fluid enters the coil 20 in the lower left part and exits as a heated fluid in the upper right part. After passing through the liquid 15, the dry carrier gas accumulates in the gas chamber 19 at the top of the chamber and is extracted through the gas conduit 32 ".
    [0040]
    [0041] The bubble generator 44 may have a diameter, for example, of 1.25 m, and may have a plurality of holes, each with a diameter, for example, of 1 mm to generate bubbles of approximately the same diameter. The bubble generator 44 may be in the form of, for example, a sieve plate, wherein the carrier gas is pumped through the holes in the sieve plate. Alternatively, the bubble generator 44 may be in the form of a sprinkler with perforated tubes to distribute the carrier gas, wherein the sprinkler distributes the bubbles through the perforated tubes, which can extend from a central conduit. The tubes perforated in the sprayer can have, for example, a radial configuration, of multiple concentric rings, spider web or wheel type with hub and spokes, through which the carrier gas is pumped from an external source.
    [0042]
    [0043] All the components of the bubble column (for example, all the walls and the bubble generator can be angled with respect to the vertical, to, between 0 ° and 60 ° with respect to the vertical (for example, with respect to an axis along a radian that passes through the center of the earth.) Since the bubble column 14 is angled, the hydrostatic load is reduced from pgH to pgH • (cos a), where p is the density (kg / m3), g is the gravitational acceleration (9.81 m / s2) and h is the height of the liquid in the column.This reduction in hydrostatic load comes with a reduction in fluid pressure drop of up to 50 However, this pressure drop will be accompanied by a reduction in the heat transfer coefficient of the fluid side at greater angles (at> 45 °). This is because, at greater angles, the circulation of the liquid is not set up on a regular basis. However, for an optimized design , the angled configuration with lower pressure drop can provide significant savings in energy cost.
    [0044]
    [0045] In FIG. 2 shows an embodiment of a multi-stage bubble column condenser in a humidification-dehumidification (HDH) water purification system 10, wherein the dehumidifier is a multi-stage vapor mixture condenser 12 of bubble column (also called "bubbler") instead of using an indirect contact heat exchanger (as is common with conventional HDH systems) to dehumidify the wet carrier gas (e.g., moist air) and produce fresh liquid water efficiently . The carrier gas is humidified with vaporized water of a liquid composition (eg, seawater or wastewater) in the humidifier 24; and the water vapor trapped in the carrier gas is then transported through the conduit 32 'to the condenser 12 of the bubble column, where the water in the moist air condenses to produce fresh (ie, substantially pure) water.
    [0046] The liquid composition (for example, seawater) is provided from a source 16 (for example, a tank) and is circulated through the system by a pump 36, which can be mounted in the conduit 18 between the source 16 and the bubble column condenser 12. The liquid composition is passed through each stage 14 of the condenser 12 through internal ducts 20 mounted in each stage 14, where the design of each of the stages 14 can substantially coincide with that of the single-bubble bubble column step of FIG. 1. In this embodiment, the liquid composition is passed between stages 14 through adjacent external ducts 18 to preheat the liquid composition. The internal ducts 20 may have thermally conductive surfaces 23 (eg fins) that extend from the ducts 20 (as shown in FIG. 2) to increase heat transfer of the liquid in steps 14 to the liquid composition that passes through the tube coil 20. After exiting the inner tube coil 20 in the lower (first) stage 14 'of the bubble column condenser 12, the liquid composition passes through an additional conduit 18 to a heater 22 (for example, a water heater solar or a residual heat source) that further heats the liquid composition (for example, at 80 ° C) before the liquid composition is passed to the humidifier 24 and atomized and dispersed through a nozzle 26.
    [0047]
    [0048] Within the humidifier, packaging material 28 is provided in the form of, for example, vinyl polychloride (PVC) packaging to facilitate the flow of gas and to increase the surface area of the liquid that is in contact with the carrier gas to increase the portion of the vaporizable liquid that is vaporized in the carrier gas. The body of the humidifier 24 (and that of the dehumidifier 12, as well as the ducts 18 and 32) may be formed, for example, of stainless steel and is substantially vapor impermeable. In one embodiment, the humidifier 24 is substantially cylindrical with a height of approximately 2.5 m and a radius of approximately 0.5 m.
    [0049]
    [0050] The humidifier 24 and dehumidifier 12 are both modular in construction (that is, each in the form of a separate and discrete device) and are substantially thermally separated from each other. The characterization of the humidifier 24 and the dehumidifier 12 as "substantially thermally separated" should be understood as being structured for a small or no transfer of direct conductive thermal energy through the apparatus between the humidifier 24 and the dehumidifier 12, although this characterization does not exclude a mass flow that carries thermal energy (through the flow of gas and / or liquid) between the chambers. This characterization of "substantial thermal separation" thus distinguishes the apparatus from, for example, a spray vaporization apparatus, which includes a heat transfer wall shared between the humidifier and the dehumidifier. In the apparatus of this description, the humidifier 24 and the dehumidifier 12 do not need to share any common wall that facilitates the transfer of conduction heat between them.
    [0051]
    [0052] The carrier gas flows up through the chamber defined by the humidifier 24 from the port for conduit 32 "" to the port for conduit 32 ', where it exits with a higher vaporized liquid content. The humidification of the carrier gas is achieved by sprinkling the liquid composition from one or more nozzles 26 at the top of the humidifier 24 down through an area that includes packing material 28, where part of the water in the liquid composition will evaporate, while that a non-evaporated remnant of the liquid composition (e.g. brine) flows down through a rain zone to the base of the chamber defined by the humidifier 24, where the brine is drained through a conduit 18 to a 30 brine collection tank. Meanwhile, the carrier gas moves upwards through the humidifier 24 and contacts the liquid composition, particularly in the bed of the packing material 28, to humidify the carrier gas with evaporated water vapor of the liquid composition. Accordingly, the carrier gas can be saturated with water vapor before being removed from the humidifier 24 through the conduit 32 'and pumped through a compressor / blower 34 through the inlet of a first stage 14' of the condenser 12 of multi-stage bubble column In particular embodiments, an air heater and / or an air compressor or thermal steam compressor can be mounted in the duct 32 'to heat and / or compress the carrier gas before it is pumped to the dehumidifier 12. When a air compressor or a thermal steam compressor in the duct 32 ', a complementary air expander can be mounted in the duct 32 "" to expand the carrier gas as it circulates back to the humidifier 24. In other embodiments, the compressor / Blower 34 can be placed in conduit 32 "" that leads to humidifier 24 due to operational considerations.
    [0053]
    [0054] The flow of seawater through the coil 20 into the dehumidifier 12 can ensure that heat is recovered directly to preheat the liquid composition (eg, seawater in this embodiment) during the condensation process. The bubble column condenser 12 includes a plurality of stages 14, each filled with a liquid bath (eg, distilled water) through which wet and hot carrier gas is passed using a compressor / blower 34 and a generator 44 of bubbles that inject gas bubbles (or through which bubbles are injected) into the bathroom.
    [0055]
    [0056] The carrier gas charged with hot water vapor emitted from the humidifier 24 (evaporator) passes (for example, at a temperature of 70 ° C) through the conduit 32 'which extends from the top of the humidifier 24 and is bubbled to through each of the stages 14 in the dehumidifier 12, where the carrier gas is cooled and dehumidified. The carrier gas accumulates at the top of each stage 14 and is passed from an outlet at the top of each stage 14 through a conduit 32 in and through an inlet of the next stage 14 and through the generator 44 of bubbles, which generates bubbles from the carrier gas that then passes through the distilled water in step 14, and the carrier gas is then collected again at the top of the column. This process is repeated sequentially in each subsequent column.
    [0057]
    [0058] A low pressure drop in the present dehumidifier 12 can keep the pumping power low, which allows an economically viable system. This focus on maintaining low pumping power is in contrast to many bubble columns in the chemical industry, where the main concern is the transfer of mass and heat, and where the pressure drop may not be a significant design constraint. The pressure drop in the bubble chamber at each stage 14 occurs largely due to the following three factors: (1) pressure drop in the bubble generator 44, where bubbles are generated, (2) friction between the carrier gas and distilled water as bubbles rise through the liquid, and (3) the hydrostatic charge. Since the hydrostatic load is the largest contributor to the total pressure drop at a given stage 14, the height of each stage 14 (measured vertically in the orientation shown in the figures) is advantageously kept low. To obtain a pressure drop of less than 1 kPa, for example, the total height of all stages 14 amounts to less than about 1 m. Generally, this height restriction is manifested in the form of a column of bubbles of low aspect ratio, where the ratio of column height to diameter (measured horizontally in the orientation shown) is less than 1. In particular embodiments, the column diameter is 0.5 to 1 m, while column height is 0.05 to 0.1 m (for an aspect ratio of the column is approximately 0.1).
    [0059]
    [0060] The temperature of the carrier gas may fall at least 5 ° C from each stage 14 to the next in the dehumidifier 12, as it cools with the liquid bath in each stage 14. For example, in the duct 32 "from the outlet from the first stage 14 'to the second stage inlet 14 ", the carrier gas may have a temperature, for example, of approximately 60 ° C, while the carrier gas in the duct 32'" of the outlet of the second stage 14 "at the entrance of the third stage 14 '" may have a reduced temperature, for example, of approximately 50 ° C. When the carrier gas leaves the condenser 12 of the bubble column through the upper conduit 32 "", the gas Carrier returns to the bottom of humidifier 24 (with a reduced content of the vaporizable liquid), its temperature can be further reduced, for example, to approximately 30 ° C. In the initial transitional period during the start of the process, water vapor in the wet carrier gas and hot transmits latent heat to water at each stage 14 (in which a natural circulation circuit is established); and a mixed average temperature of stage 14 of water is finally reached in a stable state. Once the stable state is reached, the heat of condensation is extracted directly by the seawater that is sent through the coil 20. In this way, a direct heat recovery is achieved.
    [0061]
    [0062] When the condensed steam is water, the dehumidification of the carrier gas at each stage 14 releases water from the carrier gas to the distilled water through which the carrier gas is bubbled. Water is drained from each stage 14 (equivalent to the increase in water provided by the dehumidification of the carrier gas) through the ducts 38 to a pure water collection tank 40. Alternatively, the liquid (for example, water) can be extracted through a bath conduit in the third stage 14 "'and passed to the second stage 14" of lower temperature and extracted through another conduit from the second stage 14 "and move on to the first stage 14 ', of an even lower temperature, from which the multi-stage bubble column condenser 12 is finally extracted as a product.
    [0063]
    [0064] Although a single stage / column 14 can be used, the use of multiple stages in the bubble column condenser 12 drives the temperature at which the seawater is preheated to the maximum possible (which is the temperature of the gas inlet carrier). The effects of this step arrangement can be clearly understood through the temperature profiles in a multi-stage bubble column condenser (shown in FIG. 3) and in a single stage bubble column condenser (shown in FIG. 4), where it can be seen that the seawater outlet temperature is much higher in the graphs for the multi-stage bubble column condenser, as shown in FIG. 3. Each of the 46 (-308 K), 48 (-318 K), 50 (-327 K), 52 (-335 K), 54 (-342 K), 56 (-348 K) horizontal segments represented in FIG. 3 represents the temperature in a respective column / stage 14 in a six-stage bubble column condenser, where the horizontal axis of the graph represents a dimensionless distance from the top to the bottom of the bubble column condenser 12 (i.e. , reference line 46 represents the temperature of the highest stage 14). The diagonal line 58 represents the temperature of the seawater as it flows through the bubble column condenser 12 as a function of the distance from the top of the bubble column condenser 12. Meanwhile, it is observed that the temperature 60 in the single stage bubble column condenser (shown in FIG. 4) is substantially constant (at 323 K) throughout the bubble column condenser and approximately equal to the average of the temperatures of the inlet and outlet carrier gas.
    [0065]
    [0066] In addition, the multi-stage bubble column condenser 12 has a direct advantage of allowing the extraction / injection of seawater from the intermediate stages of the bubble column through intermediate exchange ducts 42, as shown in FIG. . 5, where the intermediate exchange conduits 42 are coupled with the bubble column condenser 12 between the first and second stages 14 'and 14 "and between the second and third stages 14" and 14 "' of a condenser system of three-stage bubble column The saline water is collected in the trays 43 'and 43 "intermediate in the respective intermediate stages in the humidifier chamber 24 and injected into the external ducts 18 through which the seawater flows between the stages 14 'and 14 "and between stages 14" and 14'", respectively. In other embodiments, the injection / extraction direction can be reversed (for example, the saline water can be extracted from the condenser 12 and injected into the humidifier 24), depending on the operating conditions Such extraction flows may allow the construction of systems that are thermodynamically balanced.In additional embodiments, the wet carrier gas can be extracted / injected instead of extracting / injecting saline water. the higher heat transfer coefficients in a bubble column condenser and at a lower final temperature difference, the apparatus described herein (such as that shown in FIG. 5) can provide superior performance in terms of dehumidification and The efficiency of it.
    [0067]
    [0068] In describing the embodiments of the invention, a specific terminology is used for reasons of clarity. For the purposes of the description, the specific terms are intended to include at least technical and functional equivalents that operate in a similar manner to achieve a similar result. In addition, in some cases where a particular embodiment of the invention includes a plurality of system elements or steps of the method, those elements or steps may be replaced with a single element or step; In the same way, a single element or step can be replaced by a plurality of elements or steps that serve the same purpose. In addition, when the parameters for various properties are specified herein for embodiments of the invention, said parameters may be set up or down in 1/100, 1/50, 1/20, 1/10, 1/5 , 1/3, 1/2, 2/3, 3/4, 4/5, 9/10, 19/20, 49/50, 99/100, etc. (or up by a factor of 1, 2, 3, 4, 5, 6, 8, 10, 20, 50, 100, etc.), or by rounded approximations thereof, unless otherwise specified. Furthermore, although this invention has been shown and described with references to particular embodiments thereof, those skilled in the art will understand that various substitutions and alterations in the form and details can be made without departing from the scope of the invention (e.g., the Condensed liquid can be a composition other than water; more or less stages can be used in the bubble column condenser; and the configuration of those stages can be easily altered).
    权利要求:
    Claims (15)
    [1]
    1. A humidification-dehumidification system (10) comprising:
    a humidifier (24) that includes a carrier gas inlet and a carrier gas outlet; a liquid inlet and a liquid outlet, wherein the liquid inlet is coupled with a source (16) of liquid; and a chamber in which the liquid introduced from the liquid inlet may come into contact with a carrier gas containing a condensable fluid in the vapor phase that is introduced from the carrier gas inlet in a countercurrent arrangement and in which a part of the liquid can be vaporized in the carrier gas;
    a bubble column vapor mixing condenser (12) that includes at least a first stage (14 ') that includes a carrier gas inlet, a carrier gas outlet and a chamber containing a bath (15) of liquid in fluid communication with the carrier gas inlet and with the carrier gas outlet, where the condenser carrier gas input is in fluid communication with the humidifier carrier gas outlet, where the condenser carrier gas outlet is in communication fluid with the humidifier carrier gas inlet, wherein the condenser carrier gas inlet is a bubble generator (44) placed in contact with the liquid bath, so that the carrier gas can bubble up through the bath of liquid from the bubble generator, overcoming a hydrostatic charge of the liquid bath, and where the exit of the carrier gas is placed with an opening for the extraction of the carrier gas by ma of the liquid bath, the bubble column vapor mixing condenser further comprising a conduit (20) extending through the liquid bath in the chamber and being coupled with the liquid source and the liquid inlet of the humidifier for the liquid to flow from the source, through the condenser chamber, where the liquid can be preheated by recovering energy from the condensation, to the humidifier; Y
    wherein the system further comprises a blower or a compressor (34) configured to pump the carrier gas: from the outlet of the carrier gas of the humidifier to the entrance of the carrier gas of the condenser through a conduit (32 '), and through the bubble generator, which allows carrier gas to bubble through the liquid bath.
    [2]
    2. The humidification-dehumidification system (10) of claim 1, wherein the bubble column vapor mixing condenser (12) further comprises a second stage (14 ") which also includes a carrier gas inlet, a carrier gas outlet and a chamber configured to contain a bath (15) of fluid in fluid communication with the carrier gas inlet and the carrier gas outlet of the second stage, wherein the carrier gas outlet of the first stage is in fluid communication with the carrier gas inlet of the second stage to facilitate the flow of carrier gas from the humidifier (24) through the chamber of the first stage and then through the chamber of the second stage before returning to the humidifier .
    [3]
    3. The humidification-dehumidification system (10) of claim 1, further comprising a bubble generator (44) coupled with the input of each stage to generate bubbles of the carrier gas in the liquid, preferably wherein the bubble generator Select from (a) a sieve plate and (b) a radial, ring, spider and wheel type sprinkler.
    [4]
    4. The humidification-dehumidification system (10) of claim 1, further comprising an intermediate exchange conduit (42) coupled with the conduit (20) between (a) the first stage (14 ') and the second stage ( 14 ") and (b) an intermediate tray (43 ', 43") in the humidifier chamber at an intermediate stage to transfer the liquid between them.
    [5]
    5. The humidification-dehumidification system (10) of claim 1, wherein the chamber containing the liquid has a height to diameter aspect ratio of less than 1.
    [6]
    6. The humidification-dehumidification system (10) of claim 1, wherein the chambers containing the liquid are angled with the vertical.
    [7]
    7. A method for condensing a fluid from a carrier gas stream, comprising:
    use a blower or compressor (34) to pass a stream of carrier gas through a humidifier (24) and out of the humidifier through a conduit (32 '), where, in the humidifier, a phase condensable fluid is added of vapor to the carrier gas stream in a chamber by introducing a liquid through a liquid inlet, thereby contacting a carrier gas containing a condensable fluid in the vapor phase that is introduced from a carrier gas inlet in a countercurrent arrangement and in which a portion of the liquid can be vaporized in the carrier gas;
    using a bubble generator (44) to bubble the carrier gas stream comprising the condensable fluid in the vapor phase through a first bath (15) of the liquid phase fluid in a first stage (14 ') of a condenser ( 12) of a column of bubbles, where the carrier gas stream comes into contact with the first bath, and where part of the vapor phase fluid in the carrier gas stream condenses in the first bath;
    draw the carrier gas stream with a reduced vapor content of the first stage of the bubble column condenser and passing the carrier gas stream back through the humidifier through a conduit (32 ""), where, in the humidifier, additional fluid in vapor phase is added to the carrier gas stream afterwards that the carrier gas stream leaves the first stage (14 '); and passing the liquid as a refrigerant through a conduit (20) that passes through the liquid in the liquid phase in the first stage to recover the energy of the condensation in the bubble column condenser to the liquid that passes through the conduit before that the liquid is introduced through the liquid inlet of the humidifier.
    [8]
    8. The method of claim 7, further comprising:
    use the blower or compressor to reintroduce the carrier gas stream to the first stage of the bubble column condenser (12) through the conduit (32 ') and pass the carrier gas stream through the first bath again.
    [9]
    9. The method of claim 7, further comprising:
    passing the carrier gas stream from the first stage (14 ') of the bubble column condenser (12) to a second stage (14 ") of the bubble column condenser;
    bubbling the carrier gas stream through a second bath of the liquid phase fluid in the second stage of the bubble column condenser, where the carrier gas stream comes into contact with the second bath, and where at least part of the Vapor phase fluid in the carrier gas stream condenses in the second bath; Y
    draw the carrier gas stream with a reduced vapor phase fluid content from the second stage of the bubble column condenser.
    [10]
    10. The method of claim 9, wherein the liquid in the first stage (14 ') is at least 5 ° C hotter than the liquid in the second stage (14 ").
    [11]
    11. The method of claim 7, wherein the fluid is water.
    [12]
    12. The method of claim 7, further comprising generating water vapor in the carrier gas stream by evaporating water from a saline solution.
    [13]
    13. The method of claim 12, wherein the saline solution is heated with a solar heater or a residual heat source before the water evaporates from the saline solution.
    [14]
    14. The method of claim 12, further comprising passing the saline solution through the conduit in each of the stages (14) of the bubble column condenser (12) to preheat the saline solution for water evaporation.
    [15]
    15. The method of claim 7, further comprising extracting the fluid in the liquid phase from the first bath.
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    同族专利:
    公开号 | 公开日
    CA2848412A1|2013-03-28|
    RU2543873C1|2015-03-10|
    US20130341810A1|2013-12-26|
    JP5818393B2|2015-11-18|
    ZA201402885B|2015-09-30|
    US20150290557A1|2015-10-15|
    US9072984B2|2015-07-07|
    JP2015231622A|2015-12-24|
    US8523985B2|2013-09-03|
    US11007455B2|2021-05-18|
    AU2012312643A1|2014-03-13|
    ES2717225T3|2019-06-19|
    KR20140062168A|2014-05-22|
    US20210228998A1|2021-07-29|
    US9320984B2|2016-04-26|
    US20130074694A1|2013-03-28|
    WO2013043568A1|2013-03-28|
    US9403104B2|2016-08-02|
    EP2758142A1|2014-07-30|
    MX2014003406A|2015-03-03|
    KR101498438B1|2015-03-03|
    IN2014DN03089A|2015-05-15|
    US8778065B2|2014-07-15|
    EP2758142B1|2019-01-09|
    AU2012312643B2|2014-06-12|
    CO6990688A2|2014-07-10|
    JP2014531312A|2014-11-27|
    US20160271518A1|2016-09-22|
    MX361787B|2018-12-17|
    EP2758142B9|2019-11-20|
    CN103842044A|2014-06-04|
    CN103842044B|2015-12-02|
    US20150260418A1|2015-09-17|
    SG11201400447QA|2014-05-29|
    US20190282922A1|2019-09-19|
    CA2848412C|2018-02-13|
    US20130075940A1|2013-03-28|
    BR112014006556A2|2017-03-28|
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    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
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